This article describes how to block secure sites such as https://www.facebook.com using the Common Name (CN) in the certificate.
NOTE: For HTTPS sites you will need to gather the common name associated to the HTTPS site. This means you’ll need to view the certificate and gather its CN.
Source Service: HTTPS
Application Object: FB Common Name (The object created earlier in this document)
Action: Reset/Drop
Connection Side: Server Side
Direction: Basic/Incoming
At this point all other fields can be modified for more specified action.
If you have issues be sure to clear cache, cookies and all offline content. Close your browser and test once more.